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Publications

2018

An optical authentication system based on imaging of excitation-selected lanthanide luminescence
Carro-Temboury, M.R.; Arppe,R.; Vosch, T.; Sørensen, T.J.
Science Advances 2018, 4, e1701384
Open Access: http://advances.sciencemag.org/content/4/1/e1701384
Highlight: Nature Photonics 2018, 12, 194

Unusually large Stokes shift for a near-infrared emitting DNA-stabilized silver nanocluster.
Bogh, S.A.; Carro-Temboury, M.R.; Cerretani, C.; Swasey, S.M.;
Copp, S.M.; Gwinn, E.G.; Vosch, T.
Methods Appl. Fluoresc. 2018, 6, 024004
Open Access: https://iopscience.iop.org/article/10.1088/2050-6120/aaa8bc

Design, Synthesis, and Time Gated Cell Imaging of Carbon-Bridged Triangulenium Dyes with Long Fluorescence Lifetime and Red Emission.
Rosenberg, M.; Rostgaard, K.R.; Liao, Z.; Madsen, A.Ø.; Martinez, K.L.: Vosch, T.; Laursen, B.W.
Chemical Science 2018, 9, 3122–3130.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2018/sc/c8sc00089a

Anti-Stokes Fluorescence Microscopy Using Direct and Indirect Dark State Formation.
Krause, S.; Carro-Temboury, M.R.; Cerretani, C.; Vosch, T.
Chem. Comm. 2018, 54, 4569-4572.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2018/cc/c8cc01521j

Upconversion Cross‐Correlation Spectroscopy of a Sandwich Immunoassay
Lahtinen, S.; Krause, S.; Arppe, R.; Soukka, T.; Vosch, T.
Chem. Eur. J. 2018, 24, 9229-9233.
open access: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201801962
Highlight: ChemistryViews

Probing heterogeneity of NIR induced secondary fluorescence from DNA-stabilized silver nanoclusters at the single molecule level.
Krause, S.; Carro-Temboury, M.R.; Cerretani, C.; Vosch, T.
PCCP 2018, 20, 16316-16319.
open acces: http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP02584C

Luminescence from lanthanide(III) ions bound to the Glycocalyx of Chinese Hamster Ovary cells
Arppe,R.; Carro-Temboury, M.R.; Hempel, C.; Vosch, T.; Sørensen, T.J.
Chem. Eur. J. 2018, 24, 11885–11889.

Photon Energy Dependent Micro-Raman Spectroscopy with a Continuum Laser Source
Krause, S.; Overgaard, M.H.; Vosch, T.
Scientific Reports 2018, 8, 11621.
Open Access: https://www.nature.com/articles/s41598-018-29921-6.pdf

Spatially Localized Synthesis and Structural Characterization of Platinum Nanocrystals Obtained Using UV Light.
Quinson, J.; Kacenauskaite, L.; Christiansen, T.L.; Vosch, T.; Arenz, M.; Jensen, K.M.Ø.
ACS Omega, 2018 3, 10351–10356.
Open Access:https://pubs.acs.org/doi/pdf/10.1021/acsomega.8b01613

NIR Induced Modulation of the Red Emission from Erbium Ions for Selective Lanthanide Imaging.
Krause, S.; Koerstz, M.; Arppe-Tabbara, R.; Soukka, T.; Vosch, T.
Methods Appl. Fluoresc. 2018, 6, 044001.
Open Access: https://iopscience.iop.org/article/10.1088/2050-6120/aadef1

High-Quality Reduced Graphene Oxide Electrodes for Sub-Kelvin Studies of Molecular Monolayer Junctions.
Kühnel, M.; Overgaard, M.; Hels, M.; Cui, A.; Vosch, T.; Nygård, J.; Li, T.; Laursen, B.W.; Nørgaard, K.;
J. Phys. Chem. C 2018, accepted.

2017

UV-induced synthesis and stabilization of surfactant-free colloidal Pt nanoparticles with controlled particle size in ethylene glycol
Kacenauskaite, L.; Quinson, J.; Schultz, H.; Kirkensgaard, J.J.K.; Kunz, S.; Vosch, T.; Arenz, M.
ChemNanoMat 2017, 3, 89–93.

Probing the Absorption and Emission Transition Dipole Moment of DNA Stabilized Silver Nanoclusters
Hooley, E.N.; Carro-Temboury, M.R.; Vosch, T.
J. Phys. Chem. A 2017, 121, 963−968.

Highly Conductive Semitransparent Graphene Circuits Screen-Printed from Water-Based Graphene Oxide Ink
Overgaard, M.H.; Kühnel, M.; Hvidsten, R.; Petersen, S.V.; Vosch, T.; Nørgaard, K.; Laursen, B.W.
Adv. Mater. Technol. 2017, 2, 1700011.

Ultrafast coherence transfer in DNA-templated silver nanoclusters
Thyrhaug, E.; Bogh, S.A.; Carro-Temboury, M.R. Madsen, C.S.; Vosch, T.; Zigmantas, D.
Nature Communications 2017, 8, 15577.
Open Access: https://www.nature.com/articles/ncomms15577.pdf

Excited-State Relaxation and Förster Resonance Energy Transfer in an Organic Fluorophore/Silver Nanocluster Dyad
Bogh, S.A.; Cerretani, C.; Kacenauskaite, L.; Carro-Temboury, M.R.; Vosch, T.
ACS Omega, 2017, 2, 4657–4664.
Open Access: https://pubs.acs.org/doi/pdf/10.1021/acsomega.7b00582

Micro-Raman spectroscopy for the detection of stacking fault density in InAs and GaAs nanowires.
Tanta, R.; Lindberg, C.; Lehmann, S.; Bolinsson, J.; Carro-Temboury, M.R.; Dick, K.A.; Vosch, T.; Jespersen, T.S.; Nygard, J.
Phys. Rev. B 2017, 96, 165433.

Temperature Dependent Excited State Relaxation of a Red Emitting DNA-Templated Silver Nanocluster.
Cerretani, C.; Carro-Temboury, M.R.; Krause, S.; Bogh, S.A.; Vosch, T.
Chem. Comm. 2017, 53, 12556.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2017/cc/c7cc06785b

Investigating dye performance and crosstalk in fluorescence enabled bioimaging using a model system.
Arppe, R.; Carro-Temboury, M.R.; Hempel, C.; Vosch, T.; Sørensen, T.J.
PLoS ONE, 2017, 12, e0188359.
Open Access: http://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0188359&type=printable

Creating infinite contrast in fluorescence microscopy by using lanthanide centered emission
Carro-Temboury, M.R.; Arppe, R.; Hempel, C.; Vosch, T.; Sørensen, T.J.
PLoS ONE, 2017, 12, e0189529.
Open Access: http://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0189529&type=printable

2016

Probing DNA-Stabilized Fluorescent Silver Nanocluster Spectral Heterogeneity by Time-Correlated Single Photon Counting.
Carro Temboury, M.R.; Paolucci, V.; Hooley, E.N.; Latterini, L.; Vosch, T.
Analyst 2016, 141, 123–130.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2015/an/c5an02011e

Tuning the response of non-allowed Raman modes in GaAs nanowires.
Amaduzzi, F.; Alarcón-Lladó, E.; Hautmann, H.; Tanta, R.; Matteini, F.; Tütüncüoğlu, G.; Vosch, T.; Nygard, J.; Jespersen, T.; Uccelli. E.; Fontcuberta i Morral, A.
J. Phys. D: Appl. Phys. 2016, 49, 095103.

Synthesis Mechanism and Light Influence on Platinum Nanoparticles Synthesis at Room Temperature.
Kacenauskaite, L.; Swane, A.A.; Kirkensgaard, J.J.K.; Fleige, M.; Kunz, S.; Vosch, T.; Arenz, M.
ChemNanoMat 2016, 2, 104–107.

On the structural composition and stability of Fe-N-C catalysts prepared by an intermediate acid leaching.
Kramm, U.I.; Zana, A.; Vosch, T.; Fiechter, S.; Arenz, M.; Schmeißer, D.
Journal of solid state electrochemistry 2016, 20, 969-981.

Synthesis, Ensemble and Single Molecule Characterization of a Diphenyl-Acetylene Linked Terrylenediimide Dimer.
Kennes, K; Baeten, Y.; Stappert, S.; Müllen, K.; Hofkens, J.; Van der Auweraer, M.; Vosch, T.; Fron, E.
J. Phys. Chem. B 2016, 120, 2333−2342.

The colloidal tool-box approach for fuel cell catalysts: utilizing graphitized
carbon supports.
Zana, A.; Vosch, T.; Arenz, M.
Electrochimica Acta 2016, 197, 221–227.

Emissive Photoconversion Products of an Amino-triangulenium Dye
Liao, Z.; Bogh, S.A.; Santella, M.; Rein, C.; Sørensen, T.S.;
Laursen, B.W.; Vosch, T.
J. Phys Chem A 2016, 120, 3554−3561.

Morphology and composition of oxidized InAs nanowires studied by combined Raman spectroscopy and transmission electron microscopy.
Tanta, R.; Kanne, T.; Amaduzzi, F.; Liao, Z.; Madsen, M.; Alarcón-Lladó, E.; Krogstrup, P.; Johnson, E.; Fontcuberta i Morral, A.; Vosch, T.; Nygård, J.; Jespersen, T.
Nanotechnology 2016, 27, 305704.

A Comparison of Single-Molecule Emission in Aluminum and Gold Zero-Mode Waveguides.
Martin, W.E.; Srijanto, B.R.; Collier, C.P.; Vosch, T.; Richards, C.I.
J. Phys. Chem. A. 2016, 120, 6719-6727.

Photophysical Properties of Fluorescent Core Dendrimers Controlled by Size.
Paolucci, V.; Mejlsøe, S.L.; Ficker, M.; Vosch, T.; Christensen, J.B.
J. Phys. Chem. B. 2016, 120, 9576-9580.

Modification of σ-Donor Properties of Terminal Carbide Ligands Investigated Through Carbide–Iodine Adduct Formation.
Reinholdt, A.; Vosch, T.; Bendix, J.
Ang. Chem. Int. Ed. 2016, 55, 12484–12487.

Peptide-Stabilized, Fluorescent Silver Nanoclusters: Solid-Phase Synthesis and Screening.
Gregersen, S.; Vosch, T.; Jensen, K.J.
Chem. Eur. J. 2016,  22, 18492–18500.

2015

Modulation of fluorescence signals from biomolecules along nanowires due to interaction of light with oriented nanostructures.
Frederiksen, R.; Alarcon-Llado, E.; Madsen, M.H.; Rostgaard, K.R.; Krogstrup, P.; Vosch, T.; Nygård, J.; Fontcuberta i Morral, A.; Martinez, K.L.
Nano Letters 2015, 15, 176−181.
Highlight: ACS Nano 2018

Spectrally Resolved Confocal Microscopy using Lanthanide Centred near-IR Emission.
Liao, Z.; Tropiano, M.; Mantulnikovs, K.; Faulkner, S.;
Vosch, T.; Sørensen, T.J.
Chem. Commun. 2015, 51, 2372-2375.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2014/cc/c4cc09618e

Reduced graphene oxide for Li-air batteries:
The effect of oxidation time and reduction conditions for graphene oxide.
Storm, M.M.; Overgaard, M.; Younesia, R.; Reeler, N.E.A.; Vosch, T.; Nielsen, U.G.; Edström, K.; Norby, P.
Carbon 2015, 85, 233-244.

Spatial distribution and temporal evolution of DRONPA-fused SNAP25 clusters in adrenal chromaffin cells
Antoku, Y.; Dedecker, P.; Pinheiro, P.S.; Vosch, T.; Sørensen, J.B.
Photochem. Photobiol. Sci., 2015, 14, 1005-1012.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2015/pp/c4pp00423j

Single-Molecule Characterization of Near-Infrared-Emitting Silver Nanoclusters
Hooley, E.N.; Paolucci, V.; Liao, Z.; Carro  Temboury, M.R.; Vosch, T.   
Adv. Opt. Mat., 2015, 3, 1109-1115.
Open Access: https://onlinelibrary.wiley.com/doi/10.1002/adom.201500048/pdf

Lipid-conjugated fluorescent pH sensors for monitoring pH changes in reconstituted membrane systems.
Kemmer, G.C.; Bogh, S.A.; Urban, M.; Palmgren, M.G.; Vosch, T.; Schiller, J.; Pomorski, T.G.
Analyst, 2015, 140, 6313-6320.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2015/an/c5an01180a

Time-resolved confocal microscopy using lanthanide centred near-IR emission.
Liao, Z.; Tropiano, M.; Faulkner, S.; Vosch, T.; Sørensen, T.J.
RSC Advances, 2015, 5, 70282-70286.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2015/ra/c5ra15759e

Gold nanoparticles assembled with dithiocarbamate-anchored molecular wires.
Reeler, N.E.A.; Lerstrup, K.A.; Somerville, W.; Speder, J.; Petersen, S.V.; Laursen, B.W.; Arenz, M.; Qiu, X.; Vosch, T.; Nørgaard, K.
Scientific Reports 2015, 5, 15273.
Open Access: https://www.nature.com/articles/srep15273.pdf

Thermally activated LTA(Li)–Ag zeolites with water-responsive photoluminescence properties.
Coutino-Gonzalez, E.; Baekelant, W.; Grandjean, D.; Roeffaers, M.B.J.; Fron, E.; Aghakhani, M.S.; Bovet, N.; van der Auweraer, M.; Lievens, P.; Vosch, T.; Sels, B.; Hofkens, J.
J. Mater. Chem. C 2015, 3, 11857-11867.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2015/TC/C5TC02723C

Raman spectroscopy and electrical properties of InAs nanowires with local oxidation enabled by substrate micro-trenches and laser irradiation.
Tanta, R.; Madsen, M.H.; Liao, Z.; Krogstrup, P.;  Vosch, T.; Nygård, J.; Jespersen, T.S.
Applied Physics Letters 2015, 107, 243101.

2014

A surface-bound molecule that undergoes optically biased Brownian rotation.
Hutchison, J.A.; Uji-i, H.; Deres, A.; Vosch, T.; Rocha, S.; Müller, S.; Bastian, A.A.; Enderlein, J.; Nourouzi, H.; Li, C.; Herrmann, A.; Müllen, K.; De Schryver, F.; Hofkens, J.
Nature Nanotechnology 2014, 9, 131–136.

Core-shell TiO2@C: towards alternative supports as replacement for high surface area carbon for PEMFC catalysts.
Zana, A.; Rüdiger, C.; Kunze-Liebhäuser, J.; Granozzi, G.; Reeler, N.E.A.; Vosch, T.; Kirkensgaard, J.J.K.; Arenz, M.
Electrochimica Acta 2014, 139, 21-28.

Fabrication of silver nanoparticles with limited size distribution on TiO2
containing zeolites.
Mazzocut, A.; Coutino-Gonzalez, E.; Baekelant, W.; Sels, B.F.; Hofkens J.; Vosch, T.
PCCP 2014, 16, 18690-18693.
Open Access: http://pubs.rsc.org/en/content/articlepdf/2014/cp/c4cp02238f

Photophysical Investigation of Cyano-Substituted Terrylenediimide Derivatives.
Kennes, K.; Baeten, Y.; Vosch, T.; Sempels, W.; Yordanov, S.; Stappert, S.; Chen, L.; Müllen, K.; Hofkens, J.; Van der Auweraer, M.; Fron, E.
J. Phys Chem B. 2014, 118, 14662−14674.

2013

Green emitting photoproducts from Terrylene Diimide after red illumination.
Liao, Z.; Hooley, E.N.; Chen, L.; Stappert, S.; Müllen, K.; Vosch, T.
J. Am. Chem. Soc. 2013, 135, 19180-19185.

Investigating the corrosion of high surface area carbons duringstart/stop fuel cell conditions: A Raman study.
Zana, A.; Spedera, J.; Reeler, N.E.A.; Vosch, T.; Arenz, M.
Electrochimica Acta 2013, 114, 455–461.

Ultrathin Reduced Graphene Oxide Films as Transparent Top-Contacts for Light Switchable Solid-State Molecular Junctions
Li, T.; Jevric, M.; Hauptmann, J.R.; Hviid, R.; Wei, Z.; Wang, R.; Reeler, N.E.A.; Thyrhaug, E.; Petersen, S.; Meyer, J.A.S.; Bovet, N.; Vosch, T.; Nygård, J.; Qiu, X.; Hu, W.; Liu, Y.; Solomon, G.C.; Kjaergaard, H.G.; Bjørnholm, T.; Nielsen, M.B.; Laursen, B.W.; Nørgaard, K.
Advanced Materials 2013, 25, 4164-4170.

2012

The beneficial effect of CO2 in the low temperature synthesis of high quality carbon nanofibers and thin multiwalled carbon nanotubes from CH4 over Ni catalysts.
Corthals, S.; Van Noyen, J.; Geboers, J.; Vosch, T.; Liang, D.; Ke, X.; Hofkens, J.; Van Tendeloo, G.; Jacobs, P.; Sels, B.
Carbon 2012, 50, 372-384.

Luminescence of oxyfluoride glasses co-doped with Ag nanoclusters and Yb3+ ions.
Tikhomirov, V.K.; Vosch, T.; Fron, E.; Rodríguez, V.D.; Velázquez, J.J.; Kirilenko, D.;
Van Tendeloo, G.;  Hofkens, J.; Van der Auweraer, M.; Moshchalkov,V.V.
RSC Advances 2012, 2, 1496–1501.

Solution-processed Ultrathin Chemically Derived Graphene Films as Soft Top Contacts for Solid-State Molecular Electronic Junctions.
Li, T.; Hauptmann, J.R.; Wei, Z.; Petersen, S.; Bovet, N.; Vosch, T.; Hu, W.; Liu, Y;.  Nygård, J.; Bjørnholm, T.; Nørgaard, K.; Laursen, B.W.
Advanced Materials 2012, 24, 1333-1339.

End-to-end assembly of gold nanorods via oligopeptide linking and surfactant control.
Jain,T.; Roodbeen, R.; Reeler, N.E.A.; Vosch, T.; Jensen, K.J.; Bjørnholm, T.; Nørgaard, K.
Journal of Colloid and Interface Science, 2012, 376, 83–90.

Design Aspects of Bright Red Emissive Silver Nanoclusters/DNA Probes for MicroRNA Detection. Shah, P.; Rørvig-Lund, A.; Chaabane, S.A.; Thulstrup, P.W.; Kjaergaard, H.G.; Fron, E.; Hofkens, J.; Yang,  S.W.; Vosch, T.
ACS Nano 2012, 6, 8803-8814.

2011

Energy Transfer Pathways in a Rylene-Based Triad
Fron, E.; Puhl, L.; Oesterling, I.; Li, C.; Müllen, K.; De Schryver, F.C.; Hofkens, J.; Vosch, T.
ChemPhysChem 2011, 12, 595-608.

Graphitic nanocrystals inside the pores of mesoporous silica: Synthesis, characterization and an adsorption study
de Clippel, F.; Harkiolakis, A.; Vosch, T.; Ke, X.; Giebeler, L.; Oswald, S.; Houthoofd, K.; Jammaer, J.; Van Tendeloo, G.; Martens, J.A.; Jacobs,P.A.; Baron, G.V.; Sels, B.F.; Denayer, J.F.M.
Microporous Mesoporous Mater. 2011, 144, 120–133

A statistical approach to inelastic electron tunneling spectroscopy on fullerene-terminated molecules
Fock, J.; Sørensen, J.K.; Emanuel Lörtscher, Vosch, T.; Martin, C.A.; Riel, H.; Kilså, K.; Bjørnholm, T.; van der Zant, H.
PCCP 2011, 13, 14325-14332.

Chiral non-periodic surface-confined molecular nanopatterns revealed by scanning tunnelling microscopy
Saletra, W.J.; Xu, H.; Vosch, T.; De Feyter, S.; Amabilino, D.B.
CrystEngComm 2011, 13, 5578-5583.

Single Layer vs Bilayer Graphene: A Comparative Study of the Effects of Oxygen Plasma Treatment on Their Electronic and Optical Properties
Nourbakhsh, A.; Cantoro, M.; Klekachev, A.V.; Pourtois, G.; Vosch, T.; Hofkens, J; van der Veen, M.H.; Heyns, M.M.; De Gendt, S.; Sels, B.F.
J. Phys Chem C. 2011, 115, 16619-16624.

Rapid Detection of MicroRNA by a Silver Nanocluster DNA Probe
Yang, S.W.; Vosch, T.
Analytical Chemistry 2011, 83, 6935–6939.

2010

Selective Bifunctional Catalytic Conversion of Cellulose over Reshaped Ni Particles at the Tip of Carbon Nanofibers
Van de Vyver, S.; Geboers, J.; Dusselier, M.; Schepers, H.; Vosch, T.; Zhang, L.; Van Tendeloo, G.; Jacobs, P.A.; Sels, B.F.
ChemSusChem 2010, 3, 698-701.

Molecular Sieve Properties of Mesoporous Silica with Intraporous Nanocarbon
de Clippel, F.; Harkiolakis, A.; Vosch, T.; Baron, G.; Jacobs, P.A.; Denayer, J.F.M.; Sels, B.F.
Chem. Comm. 2010, 46, 928-930

The Rylene Colorant Family – Tailored Nano-emitters for photonics research and applications
Weil, T.; Vosch, T.; Hofkens, J.; Pevena, K.; Müllen, K.
Ang. Chem. Int. Ed. 2010, 49, 9068-9093.

Transfection of Living HeLa cells with Fluorescent Poly-Cytosine Encapsulated Ag Nanoclusters.
Antoku, Y.; Hotta, J.-I.; Mizuno, H; Dickson, R.M.; Hofkens, J.; Vosch, T.
Photochem. & Photobiol. Sci. 2010, 9, 716-721

Unraveling excited state dynamics in a polyfluoreneperylenediimide copolymer.
Fron, E.; Deres, A.; Rocha, S.; Zhou, G.; Müllen, K.; De Schryver, F.C.; Sliwa, M.; Uji-i, H.; Hofkens, J.; Vosch, T.
J. Phys Chem B. 2010, 114, 1277-1286

Optical encoding of silver zeolite microcarriers.
De Cremer, G.; Sels, B.F.; Hotta, J.-I.; Roeffaers, M.B.J.; Bartholomeeusen, E.; Coutiño-Gonzalez, E.; Valtchev, V.; De Vos, D.E.; Vosch, T.; Hofkens, J.
Adv. Mat. 2010, 22, 957-960

Tuning the Fermi level of SiO2-supported single-layer graphene by thermal annealing.
Nourbakhsh, A.; Cantoro, M.; Klekachev; A.; Clemente, F.; Sorée, B.; van der Veen, M.H.; Vosch, T.; Stesmans, A.; Sels, B.; De Gendt, S.
J. Phys Chem C. 2010, 114, 6894-6900

In situ observation of the emission characteristics of zeolite hosted silver species during heat treatment.
De Cremer, G.; E.; Coutiño-Gonzalez, E.; Roeffaers, M.B.J.; De Vos, D.E.; Hofkens, J.; Vosch, T.; Sels, B.F.
ChemPhysChem 2010, 11, 1627-1631

Modified, semiconducting graphene in contact with a metal: characterization of the Schottky diode
Nourbakhsh, A.; Cantoro, M.; Hadipour, A; Vosch, T.; van der Veen, M.H.; Heyns, M.M.; Sels, B.F. De Gendt, S.
Appl. Phys. Lett. 2010, 97, 163101_1-163101_3.

Band gap opening in oxygen plasma-treated graphene
Nourbakhsh, A.; Cantoro, M.; Vosch, T.; Pourtois, G.; Clemente, F.; van der Veen, M.H.; Hofkens, J; Heyns, M.M.; De Gendt, S.; Sels, B.F.
Nanotechnology 2010, 21, 435203_1-435203_9.